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Page Title: Material Safety Data Sheets (MSDS)
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Chemical Safety
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Photography (Basic) - Introduction to photography and other graphic techniques
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Summary

Ventilation-In a chemical mixing area, exhaust ventilation must be provided The exhaust vent must draw vapors away from the person mixing the chemicals and provide a complete air change once every 3 minutes (20  changes  per  hour). Mixing  and  diluting-Strong  acids  and  strong oxidizing  agents  may  react  violently  or  produce explosive products. Toxic gases may be created when acid is mixed with such chemicals as sulfides, cyanides, nitrates, and nitrites. Diluting acids with water can generate considerable heat; acid should always be added to water, not water to acid. The addition should be done slowly  with  constant  stirring. Never smell a chemical directly from the bottle; instead, hold the bottle at a distance from your nose and sniff  its  contents  cautiously  rather  than  inhale  directly. Never taste a chemical. Handle  all  chemicals  cautiously;  many  can produce  burns  or  skin  irritation. MATERIAL  SAFETY  DATA  SHEETS (MSDS) In  addition  to  the  precautions  listed  previously, every  person  in  your  imaging  facility  must  be completely familiar with the Material Safety Data Sheets (MSDS) for each chemical solution used in your photographic production. The MSDS are provided by all the manufacturers of hazardous materials. You are required to have the MSDS for each solution. The Occupational  Safety  and  Health  Administration (OSHA),  as  well  as  your  safety  officer,  performs periodic  safety  inspections  of  your  imaging  facility. Every  person  is  responsible  for  the  location  and information  contained  in  the  MSDS.  MSDS  are generally  broken  down  into  12  sections  as  follows: 1.   Product Information 2.   Component Information 3.   Precautionary Label Statements 4.   Physical Data 5.   Fire and Explosion Hazard 6.   Reactivity  Data 7.   Toxicological   Properties 8.   Protection and Preventive Measures 9.   Storage and Disposal 10. First Aid 11. Transportation 12.  Preparation  Information It should be noted that separate MSDS may apply to   working   solutions   and   stock   solutions   or concentrates.   Be certain that the MSDS apply to the chemical  you  are  in  contact  with. ENVIRONMENTAL   ISSUES The Environmental Protection Agency (EPA) has tightened  regulations  drastically  and  they  have  a substantial impact on the way imaging facilities conduct business.  All  Hazardous  Materials  (HAZMAT)  must  be handled  in  complete  compliance  with  EPA  regulations. The  regulations  and  tolerances  differ  from  state  to  state and base to base. It is important that you comply with the regulations in your local area DISPOSING OF HAZARDOUS MATERIALS Before you pour photographic chemicals down the drain or throw material in the dumpster or over the side, you must be certain that you are not violating any hazardous material handling or disposal procedures. You   should   be   completely   familiar   with   the environmental protection standards and the Ship's Hazardous Material List for all items that apply to your command. EPA regulations state that anyone violating environmental  protection  regulations  can  be  personally accountable and fined. When you have ANY doubt, ask your supervisor before disposing of the material(s). The  MSDS  provide  information  on  how  to neutralize   and   clean   up   spill   containment   of photographic chemicals. When handling and cleaning up  chemical  spills,  be  sure  you  follow  all  safety precautions mentioned previously. It is important that any chemical spill be cleaned up immediately because many  chemicals  are  extremely  corrosive.  These chemicals may damage or stain the surfaces with which they come into contact. Consult your local directives on disposing of materials used to clean up chemical spills as  well  as  the  chemicals  themselves. SILVER  RECOVERY Silver  contained  in  photographic  emulsions  and used fixers and bleaches are considered hazardous 9-11

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