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Page Title: HAZARDOUS MATERIALS USER’S GUIDE (HMUG)
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Chapter 4 Hazardous Materials
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Firecontrolman Volume 01-Administration and Safety
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SAFETY PRECAUTIONS FOR HAZARDOUS MATERIALS

materials with which they work. This law also pertains t o    F e d e r a l    c i v i l i a n    a n d    m i l i t a r y    p e r s o n n e l . Manufacturers   must   provide   hazardous   material information for all hazardous materials they produce and must make a Material Safety Data Sheet (MSDS) available to the users of each hazardous material. In  the  Navy,  MSDSs  are  provided  in  a  computer database   on   compact   disk   read-only   memory (CD-ROM) entitled “Hazardous Material Control and Management   (HMC&M)   System.” The   CD-ROM contains   the    Hazardous   Material   User’s   Guide (HMUG),   Ships’  Hazardous  Material  List  (SHML), Shipboard Safety Equipment Shopping Guide, and the Hazardous   Material   Information   System   (HMIS), which provides over 70,000 MSDSs for materials used within the DOD. The   MSDS   must   be   available   to   all   users   of hazardous  materials  and  their  supervisors;  therefore, the   CD-ROM   containing   the   HMC&M   database   is provided  on  board  every  ship  and  shore  station.  The MSDS is used to train hazardous material users on the dangers and precautions of that material. Each MSDS contains the following information: ·   General  information,  including  an  emergency phone number for the material’s manufacturer. ·   Ingredients and identity information. ·   Physical and chemical characteristics. ·   Fire and explosion hazard data. ·   Health  and  hazard  data,  including  first aid. ·   Precautions for safe handling and use. ·   Control measures, including protective equipment. ·   Transportation data. ·   Disposal data. ·   Label data. Your   hazardous   material   control   supervisor   or hazardous  material/hazardous  waste  coordinator  can provide you with an MSDS upon request. Ashore, the MSDSs  for  each  work  center  are  located  within  the work area. Aboard ship, MSDSs for every item of HM aboard  are  available  either  through  the  HMIS  or  by hard copy for open purchased items. Supervisors must provide instruction in MSDS understanding and use, and   personnel   using   HM   must   be   trained   on   the dangers and precautions contained within the MSDS before they actually use those materials. HAZARDOUS MATERIALS USER’S GUIDE (HMUG) The  Hazardous Materials User’s Guide (HMUG) provides   safety   data   for   hazardous   materials commonly used on ships. The HMUG supplements the information   contained   in   the   Material   Safety   Data Sheets (MSDSs). Always refer to the MSDS first. Then use the HMUG to clarify any MSDS information you do not understand. The  HMUG  provides  compatibility  information, control measures, safety precautions, health hazards, spill control, and disposal guidelines for 22 hazardous material   groups   (for   instance,   adhesives,   cleaners, degreasers, paints, solvents, etc.). ·   The   Compatibility   Information   section   lists example material classes that are not compatible with the hazardous material group and the types of   reactions   that   could   occur   if   incompatible materials should mix. ·   The   Control   Measures   section   identifies   and prescribes personal protective equipment (PPE) for the chemical hazards in the group. ·   The Safety Precautions section provides safety guidance   for   using   and   storing   hazardous materials in the group. ·   The Health Hazards section points out common signs   and   effects   of   overexposure   to   the hazardous material and provides “What to do” instructions for the hazardous material user. ·   The Spill Control section provides information for responding to a spill. ·   The   Disposal   Guidelines   section   provides acceptable  methods  for  disposing  of  materials within the group. The   HMUG   does   not   include   items   such   as ammunition,   explosives,   propellants,   medical/ pharmaceutical supplies, and radioactive materials. LABELING REQUIREMENTS The Department of Defense (DOD) and the Navy both   have   standard   label   requirements   for   marking hazardous materials. Every Navy command must have a   system   to   ensure   that   hazardous   materials   are 4-2

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