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Reactor Theory (Reactor Operations) DOE-HDBK-1019/2-93 REACTOR OPERATION There is also another effect that is a consideration only on reactors that use dissolved boron in the moderator (chemical shim).   As the fuel is burned up, the dissolved boron in the moderator is slowly removed (concentration diluted) to compensate for the negative reactivity effects of fuel burnup.   This  action  results  in  a  larger  (more  negative)  moderator  temperature  coefficient  of reactivity in a reactor using chemical shim.   This is due to the fact that when water density is decreased by rising moderator temperature in a reactor with a negative temperature coefficient, it results in a negative reactivity addition because some moderator is forced out of the core. With a coolant  containing dissolved poison,  this density decrease  also results  in  some poison being  forced  out  of  the  core,  which  is  a  positive  reactivity  addition,  thereby  reducing  the magnitude of the negative reactivity added by the temperature increase.  Because as fuel burnup increases the concentration of boron is slowly lowered, the positive reactivity added by the above poison removal process is lessened, and this results in a larger negative temperature coefficient of reactivity. The following effect of fuel burnup is most predominant in a reactor with a large concentration of  uranium-238.    As  the  fission  process  occurs  in  a  thermal  reactor  with  low  or  medium enrichment, there is some conversion of uranium-238 into plutonium-239.  Near the end of core life  in  certain  reactors,  the  power  contribution  from  the  fission  of  plutonium-239  may  be comparable to that from the fission of uranium-235. The value of the delayed neutron fraction (b) for uranium-235 is 0.0064 and for plutonium-239 is 0.0021.   Consequently, as core burnup progresses, the effective delayed neutron fraction for the fuel decreases appreciably.   It follows then that the amount of reactivity insertion needed to produce a given reactor period decreases with burnup of the fuel. Shutdown A reactor is considered to be shut down when it is subcritical and sufficient shutdown reactivity exists  so  there  is  no  immediate  probability  of  regaining  criticality.    Shutdown  is  normally accomplished  by  insertion  of  some  (or  all)  of  the  control  rods,  or  by  introduction  of  soluble neutron poison into the reactor coolant. The rate at which the reactor fission rate decays immediately following shutdown is similar for all reactors  provided a large  amount of negative reactivity is  inserted.   After a large  negative reactivity addition the neutron level undergoes a rapid decrease of about two decades (prompt drop) until it is at the level of production of delayed neutrons.   Then the neutron level slowly drops off as  the delayed neutron precursors decay, and in a short while only the longest-lived precursor  remains  in  any  significant  amount. This  precursor  determines  the  final  rate  of decrease in reactor power until the neutron flux reaches the steady state level corresponding to the subcritical multiplication of the neutron source. Rev. 0 NP-04 Page 31

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