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Chemistry Volume 2 of 2
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Conductivity

CHEMISTRY PARAMETERS DOE-HDBK-1015/2-93 Reactor Water Chemistry CH-03 Rev. 0 Page 18 Figure 3  Pressurizer Total Gas Total gas concentration in the reactor coolant system   is   another   parameter   of   concern. Total gas is the sum of all gases contained in the coolant system and is made up primarily of hydrogen (H  ), nitrogen (N  ), argon (Ar), 2 2 and   oxygen   (O  ).      The   small   amounts   of 2 fission gases (Kr and Xe) normally present in the system may also contribute to the total gas concentration; however, under normal conditions these are essentially undetectable. Total    gas    is    of    concern    because    high concentrations can result in the formation of gas pockets in areas that are high points of the system where low or stagnant flow conditions exist.  Of particular concern in PWR facilities are the erosion and corrosion that may occur on   the   impellers   of   the   primary   coolant pumps.      As   the   concentration   of   gas   is increased,  the probability of the gas coming out of solution in significant amounts in areas of  low pressure is also increased.  This low pressure  condition  exists  at  the  inlet  to  the primary     coolant     pump     impeller     (where centrifugal pumps are utilized).  As these gas bubbles are forced back into solution on the high pressure side of the impeller, erosion can occur as a result of the gas bubble impinging on the impeller.  In extreme concentrations of total gas, loss of pump priming and cavitation can  occur  with  resultant  mechanical  pump damage. Reduction of total gas concentrations in PWRs is normally accomplished by the venting of a steam  space.    In  those  facilities  utilizing  a  pressurizer,  the  steam  space  in  the  top  of  the pressurizer   is   designed   to   accomplish   this   venting   operation   either   continuously   or intermittently.  This process of reducing the total gas concentration is generally referred to as degassification.  A typical PWR pressurizer with degassification piping is shown in Figure 3. Degassification  is  not  normally  required  in  a  BWR  because  of  its  design.    As  discussed previously, the boiling action in the reactor vessel strips dissolved gases from the water, and they are continuously removed in the condensing phase of the energy cycle.

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