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Specific P-V Energy
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Thermodynamics Heat Transfer and Fluid Flow Volume 1 of 3
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Heat

ENERGY, WORK, AND HEAT Thermodynamics Example: Determine the specific P-V energy of 15 lbm of steam at 1000 psi in an 18 ft3  tank. Solution: Using Equation 1-14 Pn PV m Pn (1000  lbf/in.2)  (144  in.2/ft2)  (18  ft3) 15  lbm Pn 172,800  ft   lbf/lbm Specific Enthalpy Specific enthalpy (h) is defined as h = u + Pn, where u is the specific internal energy (Btu/lbm) of the system being studied, P is the pressure of the system (lbf/ft2), and is the specific volume (ft3/lbm) of the system.   Enthalpy is usually used in connection with an "open" system problem in  thermodynamics.    Enthalpy  is  a  property  of  a  substance,  like  pressure,  temperature,  and volume, but it cannot be measured directly.  Normally, the enthalpy of a substance is given with respect to some reference value.   For example, the specific enthalpy of water or steam is given using the reference that the specific enthalpy of water is zero at .01°C and normal atmospheric pressure.    The  fact  that  the  absolute  value  of  specific  enthalpy  is  unknown  is  not  a  problem, however,  because  it  is  the  change  in  specific  enthalpy  (Dh)  and  not  the  absolute  value  that  is important  in  practical  problems.     Steam  tables  include  values  of  enthalpy  as  part  of  the information tabulated. Work Kinetic energy, potential energy, internal energy, and P-V energy are forms of energy that are properties  of  a  system.    Work  is  a  form  of  energy,  but  it  is  energy  in  transit.    Work  is  not  a property of a system.  Work is a process done by or on a system, but a system contains no work. This distinction between  the forms  of energy that  are properties of  a system and  the forms  of energy  that  are  transferred  to  and  from  a  system  is  important  to  the  understanding  of  energy transfer systems. HT-01 Page 18 Rev. 0

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