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Page Title: R-22 Monochlorodifluoromethane (CHCIF)
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R-12 Dichlorodifluoromethane (CCI,F,)
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Utilitiesman Basic Volume 02 - Manual for electric, plumbing, water and other utilities
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Refrigerant Safety

commonly  subjected  in  service.  The  cylinder  code color for R-12 is white. R-22   MONOCHLORODIFLUOROME- THANE  (CHCIF2) Monochlorodifluoromethane,    normally    called R-22,  is  a  synthetic  refrigerant  developed  for refrigeration  systems  that  need  a  low-evaporating temperature,  which  explains  its  extensive  use  in household  refrigerators  and  window  air  conditioners. R-22  is  nontoxic,  noncorrosive,  nonflammable,  and has a boiling point of -41°F at atmospheric pressure. R-22  can  be  used  with  reciprocating  or  centrifugal compressors. Water mixes readily with R-22, so larger amounts of desiccant are needed in the filter-driers to dry the refrigerant. The cylinder code color for R-22 is green. R-502   REFRIGERANT (CHCIF2/CCIF2CF3) R-502  is  an  azeotropic  mixture  of  48.8  percent R-22 and 51.2 percent R-115. Azeotropic refrigerants are  liquid  mixtures  of  refrigerants  that  exhibit  a constant maximum and minimum boiling point. These mixtures  act  as  a  single  refrigerant.  R-502  is noncorrosive,  nonflammable,  practically  nontoxic, and  has  a  boiling  point  of  -50°F  at  atmospheric pressure. This  refrigerant  can  only  be  used  with reciprocating  compressors.  It  is  most  often  used  in refrigeration  applications  for  commercial  frozen  food equipment, such as frozen food walk-in refrigerators, frozen food display cases, and frozen food processing plants. The cylinder color code for R-502 is orchid. R-134a   TETRAFLUOROETHANE (CH2FCF3) R-134a, tetrafluoroethane, is very similar to R-12, the  major  difference  is  that  R-134a  has  no  harmful influence on the ozone layer of the earth's atmosphere and  is  a  replacement  for  R-12  applications. Noncorrosive,  nonflammable,  and  nontoxic,  it  has  a boiling  point  of  -15°F  at  atmospheric  pressure.  Used for  medium-temperature  applications,  such  as  air conditioning  and  commercial  refrigeration,  this refrigerant is now used in automobile air-conditioners. The cylinder color code for R-134a is light (sky) blue. ADDITIONAL   REFRIGERANTS In  addition  to  the  previously  mentioned refrigerants,  other  less  common  refrigerants  are  used in a variety of applications. R-717 Ammonia (NH3) Ammonia, R-717, is commonly used in industrial systems. It has a boiling point of -28°F at atmospheric pressure.  This  property  makes  it  possible  to  have refrigeration at temperatures considerably below zero without  using  pressure  below  atmospheric  in  the evaporator.  Normally  it  is  a  colorless  gas,  is  slightly flammable, and, with proper portions of air, it can form an   explosive   mixture,   but   accidents   are   rare.   The cylinder color code for R-717 is silver. R-125  Pentafluoroethane  (CHCF5) Pentafluoroethane,  R-125,  is  a  blend  component used  in  low-  and  medium-temperature  applications. With  a  boiling  point  of  -55.3°F  at  atmospheric pressure,   R-125   is   nontoxic,   nonflammable,   and noncorrosive.  R-125  is  one  replacement  refrigerant for R-502. All  refrigerants  have  their  own  characteristics.  It is  extremely  important  to  charge  a  system  with  the refrigerant  specified.  Use  of  an  incorrect  refrigerant can lead to reduced efficiency, mechanical problems, and dangerous conditions. OZONE PROTECTION AND THE CLEAN AIR ACT Several  scientific  studies  conducted  in  the  1970s showed that chlorine was a leading cause of holes in the ozone. In 1987, 30 countries signed the Montreal Protocol,  which  mandated  the  phase  out  of  the production, and eventual use, of all harmful CFCs. In 1990,  the  most  significant  piece  of  legislation  affecting the  air  conditioning  and  refrigeration  industry,  the Clean  Air  Act,  was  passed.  Regulated  by  the Environmental  Protection  Agency  (EPA),  Title  VI  of the Clean Air Act states fully halogenated refrigerants (CFCs) will be phased out. It also calls for the phase out of HCFCs by the year 2030. Both of these types of refrigerants adversely affect the atmosphere, and as of July  1992,  it  is  illegal  to  discharge  refrigerant  to  the atmosphere. The production of R-12 was discontinued in December 1995, and the production of R-11, R-113, R-114, and R-115 is scheduled to be discontinued by 6-21

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