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Page Title: R-12 Dichlorodifluoromethane (CCI,F,)
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Figure 6-30.—Pressure type cut-in, cutout control switch
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Utilitiesman Basic Volume 02 - Manual for electric, plumbing, water and other utilities
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R-22 Monochlorodifluoromethane (CHCIF)

Figure 6-33.—A cutaway view of an oil separator. Refrigerants are fluids that change their state upon the application or removal of heat within a system and, in this act of change, absorb or release heat to or from an area or substance. Many different fluids are used as refrigerants.  In  recent  years,  the  most  common  has been  air,  water,  ammonia,  sulfur  dioxide,  carbon dioxide,  and  methylchloride. Today, there are three specific types of refrigerants used  in  refrigeration  and  air-conditioning  systems—(  1) Chlorofluorocarbons  or  CFCs,  such  as  R-11,  R-12,  and R-114; (2) Hydrochlorofluorocarbons or HCFCs, such as R-22 or R-123; and (3) Hydrofluorocarbons or HFCs, such  as  R-134a.  All  these  refrigerants  are "halogenated,"   which   means   they   contain   chlorine, fluorine, bromine, astatine, or iodine. Refrigerants,   such   as   Dichlorodifluoromethane (R-12),   Monochlorodifluoromethane   (R-22),   and Refrigerant  502  (R-502),  are  called  PRIMARY REFRIGERANTS because each one changes its state upon the application or absorption of heat, and, in this act of change, absorbs and extracts heat from the area or substance. The  primary  refrigerant  is  so  termed  because  it acts  directly  upon  the  area  or  substance,  although  it may  be  enclosed  within  a  system.  For  a  primary refrigerant to cool, it must be placed in a closed system in which it can be controlled by the pressure imposed upon  it. The  refrigerant  can  then  absorb  at  the temperature  ranges  desired.  If  a  primary  refrigerant were  used  without  being  controlled,  it  would  absorb heat  from  most  perishables  and  freeze  them  solid. SECONDARY  REFRIGERANTS  are  substances, such as air, water, or brine. Though hot refrigerants in themselves,  they  have  been  cooled  by  the  primary refrigeration  system;  they  pass  over  and  around  the areas  and  substances  to  be  cooled;  and  they  are returned   with   their   heat   load   to   the   primary refrigeration  system.  Secondary  refrigerants  pay  off where  the  cooling  effect  must  be  moved  over  a  long distance and gastight lines cost too much. Refrigerants  are  classified  into  groups.  The National  Refrigeration  Safety  Code  catalogs  all refrigerants into three groups—Group I – safest of the refrigerants, such as R-12, R-22, and R-502; Group II – toxic and somewhat flammable, such as R-40 (Methyl chloride)  and  R-764  (Sulfur  dioxide);  Group  III  – flammable  refrigerants,  such  as  R-170  (Ethane)  and R-290 (Propane). R-12   DICHLORODIFLUOROMETHANE (CC12F2) Dichlorodifluoromethane,  commonly  referred  to as R-12, is colorless and odorless in concentrations of less  than  20  percent  by  volume  in  air.  In  higher concentrations,  its  odor  resembles  that  of  carbon tetrachloride.   It   is   nontoxic,   noncorrosive, nonflammable,  and  has  a  boiling  point  of  -21.7°F (-29°C) at atmospheric pressure. WARNING Because  of  its  low-boiling  point  at atmospheric  pressure,  it  prevents  liquid R12 from contacting the eyes because of the possibility of freezing. One hazard of R-12 as a refrigerant is the health risk should leakage of the vapor come into contact with an open flame of high temperature (about 1022°F) and be  decomposed  into  phosgene  gas,  which  is  highly toxic. R-12 has a relatively low latent heat value, and, in smaller refrigerating machines, this is an advantage. R-12 is a stable compound capable of undergoing the physical changes without decomposition to which it is 6-20

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