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STEPS FOR PREPARING HAZARDOUS MATERIAL CONT.
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TM-38-250 Transportation of Hazardous Material on Military Fixed and Rotary Wing Craft Manual
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Air-Eligible Packaging Requirements

AFMAN 24-204(I)/TM 38-250/NAVSUP PUB 505/MCO P4030.19H/ DLAI 4145.3 33 11 DECEMBER 2001 Attachment 3 GENERAL AND HAZARD CLASS SPECIFIC PACKAGING REQUIREMENTS A3.1.  General Packaging Requirements.  The general requirements of attachment 3 are in addition to the specific packaging requirements outlined in attachments 5 through 13.  Hazardous material packaging must be authorized by this manual,  49  CFR  Part  173,  the  ICAO  Technical  Instructions,  or  the  IATA  Dangerous  Goods  Regulation  and meet the requirements outlined in this attachment. A3.1.1.    Transportability.    Securely  close  and   construct   containers  to   prevent  leakage   due   to   changes   in temperature, humidity, and altitude during transportation and in-transit handling. A3.1.1.1.    Primary  and  secondary  items  and  their  containers  (unit  or  exterior)  must    provide  protection  without deformation, leakage, or  rupture against: - Temperature changes (-40 to 65.5 degrees C [-40 to +150 degrees F]). - Pressure changes due to altitude changes (sea level to 3.7 km (12,000 feet)). - Pressure changes due to explosive decompression from 3.7 to 15.24 km (12,000 to 50,000 feet). HA3.1.1.2. Do not fill a UN specification packaging to a gross mass greater than the authorized gross mass marked on the packaging. A3.1.1.3.  Provide adequate protection for material susceptible to damage by freezing during both ground and  air operations. A3.1.2.  Compatibility.  All containers must be designed and constructed of materials that do not react with, or are not decomposed by, the material contained therein.  Plastic containers or liners must prevent permeation of contents. Plastic  packaging  or  receptacles  used  for  liquid  hazardous  materials  must  be  capable  of  withstanding,  without failure, the test specified in 49 CFR 173, appendix B, Procedure for Testing Chemical Compatibility  and Rate  of Permeation in Plastic Packagings and Receptacles. HA3.1.3.  Ullage (Outage).  Do not entirely fill containers designed to hold liquids.  When filling packagings with liquid  hazardous  material,  leave  sufficient  interior  space  (outage)  to  prevent  leakage  of  contents  or  distortion  of containers due to change of  temperature  during  transportation,  storage,  and handling.   For  flammable  liquids and other  volatile  liquids  with a high  coefficient  of  expansion,  a  minimum  outage  of  2  percent at  54  degrees  C  (130 degrees F), is required. HA3.1.4.  Closures.  Stoppers, corks, or other such friction-type closures must be held in  place  securely,  tightly, and effectively.  Secure screw-type closures on any inside plastic container to prevent the closures from loosening due to vibrations or substantial changes in temperature.  Each screw-type closure on any packaging must be secured with  pressure-sensitive  tape,  self-shrinking  plastic,  wire, a  device  designed  to  prevent the  cap  from  loosening,  or other positive means to prevent the closure from loosening due to vibration or substantial temperature change (that is, secondary seal). A3.1.5.    Inner  Packaging.    Pack,  secure,  and  cushion  inner  packagings  of  combination  packagings  to  prevent breakage  or  leakage  and  to  control  movement  within  the  outer  container.    Cushioning  material  must  not  react dangerously with the contents of the inner packagings.  Inner packagings are required as specified by the applicable packaging paragraph.  If inner packagings are not required, the packaging paragraph will state that inner packagings are not necessary.  See attachment 20 for absorbent cushioning requirements. A3.1.6.    Metal  Containers.    Unless  otherwise  specified,  the  maximum  capacity  of  metal  drums  is  208  L  (55 gallons).  Do not accept for shipment metal containers having corrosion or dents at the chime or seam, soldered, or welded area. A3.1.7.  Indicators.  Valves and indicators (with protective caps when required), which are necessary to ensure safe transportation,  must  be  installed  in  the  shipping  container.    Examples  are  relief  valves  (vacuum  or  pressure), humidity indicators, or leak indicators with adequate sensitivity to alert monitor or crew of imminent danger. A3.1.8.    Polymerizable Material.   Transportation  of  any  liquid,  solid,  or  gaseous  material  that  may  polymerize (combine  or  react  with  itself)  or  decompose  so  as  to  cause  dangerous  evolution  of  heat  or  gas  under  normal transportation conditions is prohibited.  Such materials may be offered for transportation when properly stabilized or inhibited. A3.1.9.  Solids in a Liquid Single Packaging.  A single or composite packaging which is tested and marked for liquid hazardous materials may be filled with a solid hazardous material to a gross mass, in kilograms, not exceeding the rated capacity of the packaging in liters, multiplied by the specific gravity marked on the packaging, or 1.2 if not marked.  In addition:

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