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Page Title: EXTINGUISHING AGENTS
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CLASSES OF FIRE
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FIRE-FIGHTING EQUIPMENT

Class B Class     B     fires     occur     with     flammable     liquid substances.   Examples of class B fires are gasoline, jet fuels, paints, grease, and any petroleum-based product. These  and  other  combustible  substances  do  not  leave embers  or  ashes.     Class  B  fires  are  extinguished  by providing a barrier between the burning substance and oxygen    necessary    for    combustion.    Chemical    and mechanical   foams   produce   such   a   barrier   and   are known as permanent smothering agents, but their effect is only temporary.   The application must be renewed if there  is  any  danger  of  reignition.    The  extinguishing agents  recommended  for  combating  class  B  fires  are CO2,  PKP,  Halon,  and  Aqueous  Film-Forming  Foam (AFFF). NOTE: Water by itself is  NOT  recommended for use on class B fires. Class C Class C fires are energized electrical fires that are attacked at prescribed distances by using nonconductive  agents  such  as  CO2   and  Halon  1211. The most effective tactic is to de-energize the system and handle the fire as a class A fire.  When fires are not deep seated, clean agents that pose no cleanup problem, such    as    Halon    1211    or    CO2,    are    the    preferred extinguishing agents. WARNING Water in any form, particularly salt water, is dangerous when used on electrical equipment. Class D Class   D   fires   are   combustible   metals,   such   as magnesium and titanium. Water in large quantities, as high  velocity  fog,  is  the  recommended  extinguishing agent. When   water   is   applied   to   burning   class   D materials,  there  may  be  small  explosions. The  fire fighter should apply water from a safe distance or from behind    shelter. Metal    fires    on    board    ships    are commonly associated with aircraft wheel structures. EXTINGUISHING AGENTS There   are   many   materials   that   may   be   used   as fire-fighting agents.    The primary agents discussed in the following paragraphs are the most extensively used aboard naval ships. Water Water is a cooling agent, and on board ship, the sea provides    an    inexhaustible    supply. If    the    surface temperature  of  a  fire  can  be  lowered  below  the  fuel's ignition   temperature,   the   fire   will   be   extinguished. Water is most efficient when it absorbs enough heat to raise its temperature to 212°F (100°C) or boiling point. At this temperature, the seawater will absorb still more heat until it changes to steam.   The steam carries away the heat, which cools the surface temperature. Water   in   the   form   of   fog   is   very   effective   for fire-fighting   purposes. Additionally,   water   fog   can provide protection to fire fighters from heat.   However, the fog must be applied directly to the area to be cooled if its benefits are to be realized. Water in the form of a straight stream (also called solid stream) is used to reach into smoke-filled spaces or  areas  at  a  distance  from  the  fire  fighter.     When  a straight stream is needed as an extinguishing agent, it should   be   directed   into   the   seat   of   the   fire.   For maximum   cooling,   the   water   must   come   in   direct contact with the burning material.   A straight stream is best used to break up and penetrate materials. Aqueous Film-Forming Foam (AFFF) AFFF    is    composed    of    synthetically    produced materials similar to liquid detergents. These film-forming   agents   are   capable   of   forming   water solution   films   on   the   surface   of   flammable   liquids. AFFF  concentrate  is  nontoxic  and  biodegradable  in diluted  form.    When  proportioned  with  water,  AFFF provides three fire-extinguishing advantages. 1. An aqueous film is formed on the surface of the fuel that prevents the escape of the fuel vapors. 2. The layer effectively excludes oxygen from the fuel surface. 3. The   water   content   of   the   foam   provides   a cooling effect. The primary use of AFFF is to extinguish burning flammable  or  combustible  liquid  spill  fires  (class  B). AFFF  has  excellent  penetrating  characteristics  and  is superior to water in extinguishing class A fires. Carbon Dioxide (CO2) CO2    is   an   inert   gas   and   extinguishes   fires   by smothering them.   CO2  is about 1.5 times heavier than air,   which   makes   it   a   suitable   extinguishing   agent 12-3

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